Single step polymerization of conducting poly(o-toluidine) doped with  camphor sulphonic acid : Synthesis and characterization

 

 

Milind V. Kulkarni, Annamraju Kasi Viswanath* and P. K. Khanna

 

Photonics and Advanced Materials Laboratory,

Centre for Materials for Electronics Technology, (C-MET),

Panchawati, Off Pashan Road,

Pune 411 008, India

 

Abstract

 

      Single step chemical polymerization of o-toluidine was carried out by using ammonium persulphate as an oxidizing agent. This is a direct process to synthesize the conducting emeraldine salt phase of the polymer using camphor sulphonic acid as a dopant. The polymer was characterized by UV-Vis. and FT-IR spectroscopy, scanning electron microscopy, TGA/DSC, elemental analysis and conductivity measurements. This method offers a polymer having very good  physico-chemical properties with good electrical conductivity.

 

Key words: Polymers, Chemical synthesis, Spectroscopy,  Thermogravimetric analysis (TGA), Conductivity.

 

 



* Corresponding author: E-mail address: v_kasi@ hotmail.com

Phone: 91-020-25898390, 25899273; Fax: 91-020-25898180